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Beilstein J. Org. Chem. 2014, 10, 1272–1281, doi:10.3762/bjoc.10.128
Graphical Abstract
Figure 1: Selected examples of endoperoxide-containing natural products.
Scheme 1: Endoperoxide formation via cation radicals. In both examples, single electron oxidation is followed...
Scheme 2: Diversification strategy for endoperoxide synthesis by single electron transfer. E*red vs SCE [20].
Figure 2: ORTEP of 3a.
Scheme 3: Proposed mechanism for endoperoxide synthesis from tethered dienes.
Scheme 4: Competing formal [3,3] pathway.